| Einfluß der Pulsamplitude EDP [mV] auf die Empfindlichkeit (Abbildung 28) | |||||||||||
| probenid | report | EDP [mV] | Potential [V] | Zn [nA] | Potential [V] | Cd [nA] | Potential [V] | Pb [nA] | Potential [V] | Cu [nA] | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU1.REP | 10 | -0,998 | 30,38714 | -0,578 | 17,12999 | -0,38 | 9,48955 | 0,028 | 14,39068 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU1A.REP | 10 | -0,998 | 28,31653 | -0,576 | 17,2966 | -0,38 | 9,36508 | 0,022 | 16,16485 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU2.REP | 20 | -1 | 48,86869 | -0,58 | 34,18771 | -0,384 | 18,55484 | 0,016 | 31,05 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU2A.REP | 20 | -1,002 | 50,84942 | -0,582 | 33,91705 | -0,386 | 18,45541 | 0,016 | 30,45428 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU3.REP | 30 | -1,006 | 64,93599 | -0,584 | 48,2835 | -0,388 | 25,36835 | 0,008 | 43,70841 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU4.REP | 40 | -1,012 | 75,73735 | -0,588 | 60,2005 | -0,392 | 32,0118 | 0 | 56,31353 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU5.REP | 50 | -1,02 | 78,57447 | -0,594 | 72,61699 | -0,4 | 38,4767 | -0,006 | 68,19484 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU6.REP | 60 | -1,028 | 65,05509 | -0,598 | 74,7527 | -0,402 | 38,88837 | -0,014 | 72,60311 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU7.REP | 80 | -0,608 | 82,46842 | -0,416 | 42,45384 | -0,028 | 83,50542 | |||
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU8.REP | 100 | -0,622 | 83,7811 | -0,426 | 42,46275 | -0,036 | 84,50624 | |||
| 001 5ppb | Report: D:\EGG\LM\OPT\Z_CU9.REP | 120 | -0,64 | 80,29238 | -0,436 | 39,11059 | -0,05 | 77,70225 | |||
| Einfluß der Pulsamplitude ESWV[mV] auf die Empfindlichkeit (Abbildung 35) | |||||||||||
| probenid | report | ESWV[mV] | Potential [V] | Zn [nA] | Potential [V] | Cd [nA] | Potential [V] | Pb [nA] | Potential [V] | Cu [nA] | |
| 1577_2 | Report: D:\EGG\LM\SWV\1577_6.REP | 10 | -0,946 | 14993,9092 | -0,572 | 132,36727 | -0,382 | 34,63466 | 0,034 | 37788,06 | |
| 1577_2 | Report: D:\EGG\LM\SWV\1577_7.REP | 20 | -0,948 | 28256,9805 | -0,572 | 227,88142 | -0,37 | 49,34335 | 0,036 | 74832,88 | |
| 1577_2 | Report: D:\EGG\LM\SWV\1577_7A.REP | 25 | -0,946 | 34442,8965 | -0,564 | 264 | -0,376 | 65,23669 | 0,038 | 95498,33 | |
| 1577_2 | Report: D:\EGG\LM\SWV\1577_8.REP | 30 | -0,954 | 38571,1015 | -0,57 | 284,4409 | -0,374 | 68,203 | 0,036 | 104417,1 | |
| 1577_2 | Report: D:\EGG\LM\SWV\1577_9.REP | 50 | -0,966 | 46169,8554 | -0,578 | 303,466 | -0,382 | 56,0583 | 0,032 | 133415,2 | |
| Einfluß der Pulsamplitude ESWV[mV] auf die Empfindlichkeit (Abbildung 36) | |||||||||||
| report | ESWV[mV] | Potential [V] | Zn [nA] | Potential [V] | Cd [nA] | Potential [V] | Pb [nA] | Potential [V] | Cu [nA] | ||
| 8505_3 | Report: D:\EGG\LM\SWV\8505_6.REP | 10 | -0,942 | 15951,625 | -0,57 | 134,87734 | -0,37 | 28,77318 | 0,036 | 39576,61 | |
| 8505_3 | Report: D:\EGG\LM\SWV\8505_7.REP | 20 | -0,944 | 28189,168 | -0,57 | 229,76138 | -0,378 | 54,0074 | 0,036 | 75182,31 | |
| 8505_3 | Report: D:\EGG\LM\SWV\8505_7A.REP | 25 | -0,952 | 33565,9297 | -0,57 | 257,84436 | -0,374 | 56,85952 | 0,036 | 85189,3 | |
| 8505_3 | Report: D:\EGG\LM\SWV\8505_8.REP | 30 | -0,954 | 38769,3476 | -0,572 | 294,1477 | -0,376 | 66,8044 | 0,038 | 102696,8 | |
| 8505_3 | Report: D:\EGG\LM\SWV\8505_9.REP | 50 | -0,966 | 48708,0937 | -0,578 | 315,406 | -0,382 | 58,6548 | 0,034 | 134251,6 | |
| Signal in Abhängigkeit von der Depositionszeit (tel), DPASV (Abbildung 31) | |||||||||||
| report | tel | Potential [V] | Zn [nA] | Potential [V] | Cd [nA] | Potential [V] | Pb [nA] | Potential [V] | Cu [nA] | ||
| 001 5ppb | Report: D:\EGG\LM\OPT\LL3Z_C.REP | 3 | -1,016 | 78,18749 | -0,594 | 68,217 | -0,398 | 35,46368 | -0,006 | 65,44958 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\LL5Z_C.REP | 5 | -1,016 | 134,41764 | -0,594 | 102,93399 | -0,398 | 54,31983 | -0,006 | 94,63105 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\LL7Z_C.REP | 7,5 | -1,016 | 207,32804 | -0,592 | 147,63757 | -0,398 | 76,70423 | -0,002 | 130,7357 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\LL10Z_C.REP | 10 | -1,014 | 280,68475 | -0,592 | 187,92756 | -0,4 | 97,14717 | -0,006 | 163,4085 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\LL15Z_C.REP | 15 | -1,014 | 416,30645 | -0,594 | 271,96414 | -0,398 | 137,6894 | -0,002 | 234,363 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\LL20Z_C.REP | 20 | -1,014 | 548,93939 | -0,594 | 350,04937 | -0,398 | 174,7791 | -0,002 | 298,5692 | |
| 001 5ppb | Report: D:\EGG\LM\OPT\LL30Z_C.REP | 30 | -1,012 | 788,99597 | -0,594 | 485,94076 | -0,398 | 240,1427 | 0,002 | 420,62 | |
| Abhängigkeit der Signalhöhe von der Salpetersäurekonzentration (Abbildung 29) | |||||||||||
| pH | Potential [V] | Zn [nA] | Potential [V] | Cd [nA] | Potential [V] | Pb [nA] | Potential [V] | Cu [nA] | |||
| 2,26 | -1,022 | 146,49032 | -0,6 | 86,07697 | -0,4 | 48,65696 | 0,012 | 81,37493 | |||
| 2,07 | -1,02 | 146,59094 | -0,6 | 87,48546 | -0,404 | 49,317 | 0,006 | 90,60202 | |||
| 1,85 | -1,024 | 143,91012 | -0,602 | 91,02533 | -0,406 | 50,39943 | 0,004 | 101,9949 | |||
| 1,71 | -1,024 | 171,92962 | -0,606 | 100,01133 | -0,406 | 55,46021 | 0 | 121,2127 | |||
| 1,61 | -1,026 | 181,53729 | -0,604 | 125,90759 | -0,408 | 60 | -0,006 | 154,2206 | |||
| 1,53 | -1,026 | 173 | -0,604 | 118 | -0,408 | 58,53693 | -0,002 | 151 | |||
| 1,45 | -1,028 | 171,78208 | -0,606 | 115,05757 | -0,408 | 59 | -0,006 | 149 | |||
| 1,27 | -1,03 | 173 | -0,608 | 114,22905 | -0,412 | 62,17618 | -0,006 | 153 | |||
| Abhängigkeit der Signalhöhe von der Perchlorsäurekonzentration (Abbildung 30) | |||||||||||
| pH | Potential [V] | Zn [nA] | Potential [V] | Cd [nA] | Potential [V] | Pb [nA] | Potential [V] | Cu [nA] | |||
| 2,36 | -1,038 | 138,65118 | -0,596 | 82,81941 | -0,398 | 43,10875 | 0,022 | 59,07014 | |||
| 2,12 | -1,022 | 143,35655 | -0,6 | 83,95368 | -0,402 | 48,05841 | 0,014 | 67,10714 | |||
| 1,88 | -1,022 | 154,28234 | -0,602 | 94,55822 | -0,404 | 53,26668 | 0,012 | 77,54276 | |||
| 1,7 | -1,024 | 160,75015 | -0,604 | 97,19814 | -0,406 | 54,64065 | 0,01 | 81,57347 | |||
| 1,58 | -1,024 | 169,37823 | -0,604 | 103,35886 | -0,406 | 60,48806 | 0,008 | 87,50792 | |||
| 1,5 | -1,026 | 168,86734 | -0,606 | 101,51682 | -0,406 | 57,24748 | 0,008 | 88,00204 | |||
| 1,43 | -1,026 | 170,99349 | -0,606 | 101,56527 | -0,406 | 57,12804 | 0,008 | 89,48188 | |||
| 1,23 | -1,028 | 155,7485 | -0,606 | 100,44857 | -0,408 | 56,43012 | 0,004 | 92,88162 | |||